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Influence of Al_2O_3 on Precipitation of Cr~(6+) Compound in Ca-Cr-O System

作者:YASUHIRO HOSHIYAMA;TOMOYUKI MAEDA;AKIRA YAMAGUCHI;

作者单位:Okayama Ceramics Research Foundation, Ryukoku University;Okayama Ceramics Research Foundation, Ryukoku University;Okayama Ceramics Research Foundation, Ryukoku University

刊名:Journal of the Technical Association of Refractories

ISSN:0285-0028

出版年:2010-01-05

卷:30

期:2

起页:121

止页:121

分类号:TQ175

语种:英文

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内容简介

In the case of alkaline CaO coexisting with Cr_2O_3, the production of CaCrO_4, a Cr~(6+) compound, is stimulated as the stable phase in the temperature range less than 1000°C in air atmosphere1'. On the contrary, CaCr_2O_4, a Cr~(3+)+ compound, becomes the stable phase at more than 1000°C in air atmosphere. However, in the case of the presence of Al_2O_3 together with CaO and Cr_2O_3 there is a possibility that the Cr~(6+) compound CaCrO_4 is produced even at temperatures higher than 1000°C, although there is no literature concerning details of this behavior. This research investigates the amount of Cr~(6+) compound and mineral phases generated at 1450°C in reactions between constituents in the CaO-system.

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